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http://hdl.handle.net/2445/163457
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DC Field | Value | Language |
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dc.contributor.author | Guerrero, Miguel | - |
dc.contributor.author | Ayllón, J. A. | - |
dc.contributor.author | Calvet Pallàs, Maria Teresa | - |
dc.contributor.author | Bardia, Ma. Mercedes | - |
dc.contributor.author | Pons, Josefina | - |
dc.date.accessioned | 2020-05-31T18:50:13Z | - |
dc.date.available | 2020-05-31T18:50:13Z | - |
dc.date.issued | 2017-06-08 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/2445/163457 | - |
dc.description.abstract | Three different binuclear tetracarboxylato-bridged copper(II) complexes supported by bulky pyridines ligands [Cu(m-MeCO2)2(dPy)]2 (dPy = 3-phenylpyridine (1), 2-benzylpyridine (2) and 4-acetylpyridine (3)) have been synthesised. These compounds were obtained from reaction of [Cu(MeCO2)2(H2O)]2 with pyridine-derived ligands in methanol at room temperature. All compounds were fully characterized by analytical and spectroscopic methods. The molecular structures were determined by X-ray diffraction analysis. All compounds consist of binuclear units where both Cu(II) atoms are linked by four syn-syn carboxylates bridges, showing a paddle-wheel unit, and exhibit interesting intermolecular interactions in the outer coordination sphere. | - |
dc.format.extent | 23 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier Ltd | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2017.06.010 | - |
dc.relation.ispartof | Polyhedron, 2017, vol. 134, p. 107-113 | - |
dc.relation.uri | https://doi.org/10.1016/j.poly.2017.06.010 | - |
dc.rights | cc-by-nc-nd (c) Elsevier Ltd, 2017 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Coure | - |
dc.subject.classification | Estructura cristal·lina (Sòlids) | - |
dc.subject.classification | Lligands (Bioquímica) | - |
dc.subject.other | Copper | - |
dc.subject.other | Layer structure (Solids) | - |
dc.subject.other | Ligands (Biochemistry) | - |
dc.title | Preparation, spectroscopic and structural study of copper(II) complexes derived from bulky pyridine ligands | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 676856 | - |
dc.date.updated | 2020-05-31T18:50:14Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
File | Description | Size | Format | |
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676856.pdf | 1.8 MB | Adobe PDF | View/Open |
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