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Title: | Synthesis and characterization of Pd(II), Pt(II), Cu(I), Ag(I) and Cu(II) complexes with N,O-hybrid pyrazole ligand |
Author: | Guerrero, Miguel Calvet Pallàs, Maria Teresa Font Bardia, Ma. Mercedes Pons, Josefina |
Keywords: | Lligands Cristal·lografia Propietats magnètiques Complexos metàl·lics Ligands Crystallography Magnetic properties Metal complexes |
Issue Date: | 2016 |
Publisher: | Elsevier Ltd |
Abstract: | The coordination behavior of N,O-hybrid pyrazole-based metal-organic frameworks are described. 2- (3,5-Pyridyl-1H-pyrazol-1-yl)ethanol (L) and its Pd(II), Pt(II), Cu(I), Ag(I) and Cu(II) complexes with different anions have been synthesized and characterized by elemental analysis, conductivity, mass spectrometry, IR, 1H, 13C{1H} and 195Pt{1H} NMR spectroscopies. Complex 1 was also characterized by single crystal X-ray diffraction. For complex 7 has also been possible to perform the UV-Vis and magnetic susceptibility measurements. All complexes are monomers, except the complexes obtained by reaction of the ligand (L) with M(MeCO2)2 (M = Pd(II), Pt(II)) or CuBr2, which are dimers. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2016.09.004 |
It is part of: | Polyhedron, 2016, vol. 119, p. 555-562 |
URI: | http://hdl.handle.net/2445/164365 |
Related resource: | https://doi.org/10.1016/j.poly.2016.09.004 |
ISSN: | 0277-5387 |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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