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Title: Crosslinking of poly(vinylpyrrolidone) activated by electrogenerated hydroxyl radicals: a first step towards a simple and cheap synthetic route of nanogel vectors
Author: Galia, Alessandro
Lanzalaco, Sonia
Sabatino, Maria Antonietta
Dispenza, Celia
Scialdone, Onofrio
Sirés Sadornil, Ignacio
Keywords: Oxidació electroquímica
Radicals (Química)
Electrolytic oxidation
Radicals (Chemistry)
Issue Date: 10-Dec-2016
Publisher: Elsevier B.V.
Abstract: A facile electrosynthesis route for the preparation of polymer nanogels based on the in situ production of hydroxyl radicals is reported for the first time. Electro-Fenton process with continuous H2O2 electrogeneration and Fe2+ regeneration performs better than electro-oxidation with a boron-doped diamond or dimensionally stable anode for promoting crosslinking of poly(vinylpyrrolidone).
Note: Versió postprint del document publicat a:
It is part of: Electrochemistry Communications, 2016, vol. 62, p. 64-68
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ISSN: 1388-2481
Appears in Collections:Articles publicats en revistes (Ciència dels Materials i Química Física)

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