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http://hdl.handle.net/2445/164861| Title: | Crosslinking of poly(vinylpyrrolidone) activated by electrogenerated hydroxyl radicals: a first step towards a simple and cheap synthetic route of nanogel vectors |
| Author: | Galia, Alessandro Lanzalaco, Sonia Sabatino, Maria Antonietta Dispenza, Clelia Scialdone, Onofrio Sirés Sadornil, Ignacio |
| Keywords: | Oxidació electroquímica Polímers Radicals (Química) Electrolytic oxidation Polymers Radicals (Chemistry) |
| Issue Date: | 10-Dec-2016 |
| Publisher: | Elsevier B.V. |
| Abstract: | A facile electrosynthesis route for the preparation of polymer nanogels based on the in situ production of hydroxyl radicals is reported for the first time. Electro-Fenton process with continuous H2O2 electrogeneration and Fe2+ regeneration performs better than electro-oxidation with a boron-doped diamond or dimensionally stable anode for promoting crosslinking of poly(vinylpyrrolidone). |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1016/j.elecom.2015.12.005 |
| It is part of: | Electrochemistry Communications, 2016, vol. 62, p. 64-68 |
| URI: | http://hdl.handle.net/2445/164861 |
| Related resource: | https://doi.org/10.1016/j.elecom.2015.12.005 |
| ISSN: | 1388-2481 |
| Appears in Collections: | Articles publicats en revistes (Ciència dels Materials i Química Física) |
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| 656417.pdf | 200.27 kB | Adobe PDF | View/Open |
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