Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/165286Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Esteban Jarne, Jordi | - |
| dc.contributor.author | Font Bardia, Ma. Mercedes | - |
| dc.contributor.author | Sánchez Costa, José | - |
| dc.contributor.author | Teat, Simon J. | - |
| dc.contributor.author | Escuer Fité, Albert | - |
| dc.date.accessioned | 2020-06-12T07:04:03Z | - |
| dc.date.available | 2020-06-12T07:04:03Z | - |
| dc.date.issued | 2014 | - |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | http://hdl.handle.net/2445/165286 | - |
| dc.description.abstract | In the present work, five new Ni5 clusters employing the versatile 2-pyridylcyanoxime ligand have been synthesized and chemically, structurally, and magnetically characterized. The crystallographic examination of these Ni5 clusters together with those already published in the literature, giving a total number of 14 complexes, exhibiting up to 8 different topologies for which the relationship between topology, reaction conditions and magnetic response has been analyzed. DC magnetic measurements were carried in the 300-2 K range for the new complexes and the analysis of the experimental data revealed an antiferromagnetic response for the oximato mediated interactions with a variety of ground states (S = 0, 1, 3) as function of the cluster topology. | - |
| dc.format.extent | 36 p. | - |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | American Chemical Society | - |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/ic500057j | - |
| dc.relation.ispartof | Inorganic Chemistry, 2014, vol. 53, num. 6, p. 3194-3203 | - |
| dc.relation.uri | https://doi.org/10.1021/ic500057j | - |
| dc.rights | (c) American Chemical Society , 2014 | - |
| dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
| dc.subject.classification | Lligands | - |
| dc.subject.classification | Propietats magnètiques | - |
| dc.subject.classification | Teoria quàntica | - |
| dc.subject.other | Ligands | - |
| dc.subject.other | Magnetic properties | - |
| dc.subject.other | Quantum theory | - |
| dc.title | New topologies in pentanuclear nickel/oximato clusters: structural and magnetic characterization | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/acceptedVersion | - |
| dc.identifier.idgrec | 634889 | - |
| dc.date.updated | 2020-06-12T07:04:03Z | - |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 634889.pdf | 2.28 MB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.