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http://hdl.handle.net/2445/165457
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DC Field | Value | Language |
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dc.contributor.author | Rey Carrizo, Matías | - |
dc.contributor.author | Barniol-Xicota, Marta | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Vázquez Cruz, Santiago | - |
dc.date.accessioned | 2020-06-14T12:24:57Z | - |
dc.date.available | 2020-06-14T12:24:57Z | - |
dc.date.issued | 2014-05-26 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/2445/165457 | - |
dc.description.abstract | The synthesis, chemical trapping, and dimerization of a highly pyramidalized alkene is reported. Its dimer is a unique nonacycle featuring three planar cyclobutane rings, four cyclopentane rings, and four cyclohexane rings in boat conformations. The X-ray diffraction analysis showed a H-H distance between the flagpole hydrogen atoms of 1.999 and a separation of 2.619 between the two flagpole carbon atoms. The three cyclobutane rings of the dimer were thermally stable | - |
dc.format.extent | 17 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1002/anie.201403985 | - |
dc.relation.ispartof | Angewandte Chemie-International Edition, 2014, vol. 53, num. 31, p. 8195-8199 | - |
dc.relation.uri | https://doi.org/10.1002/anie.201403985 | - |
dc.rights | (c) Wiley-VCH, 2014 | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Compostos policíclics | - |
dc.subject.classification | Alquens | - |
dc.subject.classification | Hidrocarburs | - |
dc.subject.other | Polycyclic compounds | - |
dc.subject.other | Alkenes | - |
dc.subject.other | Hydrocarbons | - |
dc.title | Dimerization of highly pyramidalized 3,4,8,9-tetramethyltetracyclo[4.4.0.03,9.04,8]dec-1(6)-ene to a hydrocarbon featuring four cyclohexane rings in boat conformation | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 641512 | - |
dc.date.updated | 2020-06-14T12:24:58Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
File | Description | Size | Format | |
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641512.pdf | 763.79 kB | Adobe PDF | View/Open |
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