Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/172412
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DC Field | Value | Language |
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dc.contributor.author | Abbasi, Parisa | - |
dc.contributor.author | Athanasopoulou, Angeliki A. | - |
dc.contributor.author | Mazarakioti, Eleni C. | - |
dc.contributor.author | Gagnon, Kevin J. | - |
dc.contributor.author | Teat, Simon J. | - |
dc.contributor.author | Escuer Fité, Albert | - |
dc.contributor.author | Pilkington, Melanie | - |
dc.contributor.author | Stamatatos, Theocharis C. | - |
dc.date.accessioned | 2020-11-29T18:44:15Z | - |
dc.date.available | 2020-11-29T18:44:15Z | - |
dc.date.issued | 2019-08-21 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/2445/172412 | - |
dc.description.abstract | The synthesis of a new {Ni8} cluster bearing tetrazolate- and azido-bridging ligands, and supported by chelating α-methyl-2-pyridine-methanol (mpmH) groups, is described herein. The reported compound has a unique trapezoidal prismatic topology, resulting from an unexpected in situ click reaction between the MeCN reaction solvent and the N3− ions under mild, room-temperature conditions. Such a click chemistry approach to the preparation of 0-D compounds is relatively unexplored and represents a fruitful strategy for the synthesis of new coordination clusters and molecule-based magnetic materials. | - |
dc.format.extent | 5 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/c9dt01998g | - |
dc.relation.ispartof | Dalton Transactions, 2019, vol. 48, num. 31, p. 11632-11636 | - |
dc.relation.uri | https://doi.org/10.1039/c9dt01998g | - |
dc.rights | (c) Abbasi, Parisa et al., 2019 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Ions | - |
dc.subject.classification | Molècules | - |
dc.subject.other | Ions | - |
dc.subject.other | Molecules | - |
dc.title | Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 693541 | - |
dc.date.updated | 2020-11-29T18:44:15Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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693541.pdf | 803.31 kB | Adobe PDF | View/Open |
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