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Title: Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
Author: Albert Mach, Joan
Granell Sanvicente, Jaime Ramón
Mínguez, Jorge
Keywords: Pal·ladi (Element químic)
Propietats òptiques
Optical properties
Issue Date: 1996
Publisher: Real Sociedad Española de Química
Abstract: The action of Pd(AcO)2 on imines derived from (R)-1-phenylethylamine, R1CR:NCHMePh, [R1 = 4-ClC6H4, R = H (1); R1 = 3,5-F2C6H3, R = H (2) and R1 = C6H5, R = Me (3)] and subsequent treatment with LiBr gives the corresponding optically active cyclopalladated dimers I. In all cases the endocyclic derivs. were formed selectively, even with the imine 2, which contains fluoro substituents on the C atom adjacent to the metalation position. The action of PPh3 on the bromo bridged compds. I affords mononuclear II.
Note: Reproducció del document publicat a:
It is part of: Anales de Quimica, 1996, vol. 92, p. 396-399
ISSN: 1575-3417
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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