Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/173441
Title: | Iron-Catalyzed Radical Intermolecular Addition of Unbiased Alkenes to Aldehydes |
Author: | Saladrigas, Mar Puig Bosch, Jordi Bonjoch i Sesé, Josep Bradshaw, Ben |
Keywords: | Alquens Catàlisi Enllaços químics Química orgànica Alkenes Catalysis Chemical bonds Organic chemistry |
Issue Date: | 5-Oct-2020 |
Publisher: | American Chemical Society |
Abstract: | The intermolecular reductive radical coupling of aldehydes with nonactivated alkenes, employing metal hydride atom transfer (MHAT) catalysis with a combination of FeII and FeIII salts, is described. This constitutes the first use of aldehydes as viable acceptor groups in MHAT reactions. The insights gained in this study led to the reexamination of the previously reported intramolecular version of the reaction, and the addition of FeII salts allowed the development of a more efficient second-generation approach. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.0c03081 |
It is part of: | Organic Letters, 2020, vol. 22, p. 8111-8115 |
URI: | http://hdl.handle.net/2445/173441 |
Related resource: | https://doi.org/10.1021/acs.orglett.0c03081 |
ISSN: | 1523-7060 |
Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) |
Files in This Item:
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705813.pdf | 781.59 kB | Adobe PDF | View/Open |
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