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DC Field | Value | Language |
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dc.contributor.author | Saechio, Supaporn | - |
dc.contributor.author | Clerac, Rodolphe | - |
dc.contributor.author | Murray, Keith S. | - |
dc.contributor.author | Phonsri, Wasinee | - |
dc.contributor.author | Ruiz Sabín, Eliseo | - |
dc.contributor.author | Harding, Phimphaka | - |
dc.contributor.author | Harding, David J. | - |
dc.date.accessioned | 2021-09-07T11:18:39Z | - |
dc.date.available | 2023-09-01T05:10:19Z | - |
dc.date.issued | 2021-09-01 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/2445/179865 | - |
dc.description.abstract | A series of Ni(II) trinuclear complexes, [Ni3(sala-X)6] (sala-X = o-[(p-X-phenylimino)methyl]phenol; X = Br 1-Br, Me 1-Me and OMe 1-OMe), have been prepared and fully characterised. X-ray crystallographic studies reveal that the complexes are composed of three face-sharing octahedral Ni(II) metal ions bridged by the phenoxide oxygens of the sala-X ligands. Magnetic studies indicate that the magnetic Ni(II) centres are ferromagnetically coupled with the substituent group having only a minor impact on the magnitude of coupling. AC susceptibility studies show no evidence of single-molecule magnet behaviour. DFT calculations also support ferromagnetic coupling with smaller Ni-O-Ni angles leading to slightly larger coupling constants in line with previous studies. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier Ltd | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2021.115321 | - |
dc.relation.ispartof | Polyhedron, 2021, vol. 205, p. 115321 | - |
dc.relation.uri | https://doi.org/10.1016/j.poly.2021.115321 | - |
dc.rights | cc-by-nc-nd (c) Elsevier Ltd, 2021 | - |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Níquel | - |
dc.subject.classification | Propietats magnètiques | - |
dc.subject.classification | Radiocristal·lografia | - |
dc.subject.other | Nickel | - |
dc.subject.other | Magnetic properties | - |
dc.subject.other | X-ray crystallography | - |
dc.title | Nickel(II) salicylaldiminates: Re-visiting a classic | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 713507 | - |
dc.date.updated | 2021-09-07T11:18:39Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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713507.pdf | 571.44 kB | Adobe PDF | View/Open |
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