Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/185030| Title: | Metal-Organic Nanocapsules with Functionalized s-Heptazine Ligands |
| Author: | Maxwell Villacorta, Lindley Andrés Martinez, Hector Martin-Rodriguez, Alejandro Gómez Coca, Silvia Rissanen, Kari Ruiz Sabín, Eliseo |
| Keywords: | Lligands Molècules Nanociència Ligands Molecules Nanoscience |
| Issue Date: | 23-Dec-2020 |
| Publisher: | American Chemical Society |
| Abstract: | A metalloorganic capsule was synthesized where the ligand is a derivative of heptazine with three carboxylic groups that are coordinated to CuII cations, forming paddle-wheel motifs. Each nanocapsule is neutral, with 12 CuII centers and 8 ligands adopting a rhombicuboctahedron shape. It has almost 3 nm diameter, and the main intermolecular interactions in the solid are π··· π stacking between the C6N7 heptazine moieties. The nanocapsules can form monolayers deposited on graphite as observed by atomic force microscopy, which confirms their stability in solution. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.0c03631 |
| It is part of: | Inorganic Chemistry, 2020, vol. 60, num. 2, p. 570-573 |
| URI: | http://hdl.handle.net/2445/185030 |
| Related resource: | https://doi.org/10.1021/acs.inorgchem.0c03631 |
| ISSN: | 0020-1669 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Institut de Química Teòrica i Computacional (IQTCUB)) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 709223.pdf | 430.95 kB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.