Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/20724
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dc.contributor.authorTakechi, Hideakicat
dc.contributor.authorArteaga Barriel, Oriolcat
dc.contributor.authorRibó i Trujillo, Josep M.cat
dc.contributor.authorWatarai, Hitoshicat
dc.date.accessioned2011-11-15T10:03:42Z-
dc.date.available2011-11-15T10:03:42Z-
dc.date.issued2011-04-29-
dc.identifier.issn1420-3049-
dc.identifier.urihttp://hdl.handle.net/2445/20724-
dc.description.abstractThe centrifugal liquid membrane (CLM) cell has been utilized for chiroptical studies of liquid-liquid interfaces with a conventional circular dichroism (CD) spectropolarimeter. These studies required the characterization of optical properties of the rotating cylindrical CLM glass cell, which was used under the high speed rotation. In the present study, we have measured the circular and linear dichroism (CD and LD) spectra and the circular and linear birefringence (CB and LB) spectra of the CLM cell itself as well as those of porphyrine aggregates formed at the liquid-liquid interface in the CLM cell, applying Mueller matrix measurement method. From the results, it was confirmed that the CLM-CD spectra of the interfacial porphyrin aggregates observed by a conventional CD spectropolarimeter should be correct irrespective of LD and LB signals in the CLM cell.eng
dc.format.extent12 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoengeng
dc.publisherMDPI Publishing-
dc.relation.isformatofReproducció del document publicat a: http://dx.doi.org/10.3390/molecules16053636cat
dc.relation.ispartofMolecules, 2011, 16(5), 3636-3647-
dc.relation.urihttp://dx.doi.org/10.3390/molecules16053636-
dc.rightscc-by, (c) Takechi et al., 2011-
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationQuiralitatcat
dc.subject.classificationDicroisme circularcat
dc.subject.classificationRefracció doblecat
dc.subject.classificationPorfirinescat
dc.subject.classificationAgregació (Química)cat
dc.subject.otherChiralityeng
dc.subject.otherCircular dichroismeng
dc.subject.otherDouble refractioneng
dc.subject.otherPorphyrinseng
dc.subject.otherAggregation (Chemistry)eng
dc.titleChiroptical measurement of chiral aggregates at liquid-liquid interface in centrifugal liquid membrane cell by Mueller matrix and conventional circular dichroism methodseng
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.identifier.idgrec595010-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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