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Title: Enantioselective formal synthesis of ent-rhynchophylline and ent-isorhynchophylline
Author: Amat Tusón, Mercedes
Ramos, Carlos
Pérez Bosch, Maria
Molins i Grau, Elies
Florindo, Pedro
Santos, Maria M. M.
Bosch Cartes, Joan
Keywords: Alcaloides
Síntesi asimètrica
Asymmetric synthesis
Issue Date: 7-Mar-2013
Publisher: Royal Society of Chemistry
Abstract: Starting from (S)-tryptophanol, a formal synthesis of ent-rhyncho-phylline and ent-isorhynchophylline, involving stereoselective cyclocondensation, spirocyclization, and alkylation reactions, and the final adjustment of the oxidation level at the oxindole and piperidine moieties, is reported.
Note: Versió postprint del document publicat a:
It is part of: Chemical Communications, 2013, vol. 49, num. 19, p. 1954-1956
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ISSN: 1359-7345
Appears in Collections:Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

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