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Title: Total synthesis of (-)-isoavenaciolide
Author: Santos, David
Ariza Piquer, Xavier
García Gómez, Jordi
Lloyd-Williams, Paul
Martínez Laporta, Agustín
Sánchez Zarzalejo, Carolina
Keywords: Biomolècules
Productes naturals
Síntesi asimètrica
Medicaments antibacterians
Natural products
Asymmetric synthesis
Antibacterial agents
Issue Date: 2013
Publisher: American Chemical Society
Abstract: An enantioselective approach to (-)-isoavenaciolide was achieved starting from 1- undecyn-3-ol. The synthesis relied upon the preparation of a chiral 4-silyloxy-2-alkenylborane by hydroboration of a protected 2,3-allenol and subsequent stereoselective addition to 2- thiophenecarboxaldehyde
Note: Versió postprint del document publicat a:
It is part of: Journal of Organic Chemistry, 2013, vol. 78, num. 4, p. 1519-1524
Related resource:
ISSN: 0022-3263
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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