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Title: Versatile methodology to hydrate alkynes, in the presence of a wide variety of functional groups, with Mercury(II) p-Toluensulfonamidate, under catalytic, mild and neutral conditions
Author: Corominas, Albert (Corominas Tarruella)
Montaña Pedrero, Ángel-Manuel
Keywords: Compostos carbonílics
Química orgànica
Carbonyl compounds
Organic chemistry
Issue Date: 2013
Publisher: Taylor and Francis
Abstract: A method to generate carbonylic compounds from alkynes under mild and neutral conditions, with excellent functional group compatibility and high yields, is described. Hydration takes place under catalytic conditions by using from 0.1 to 0.2 equivalents of the easily available and inexpensive mercury(II) p-toluensulfonamidate in a hydroalcoholic solution. After use the catalyst is iner tized and/or recycled ...
Note: Versió postprint del document publicat a:
It is part of: Synthetic Communications, 2013, vol. 43, num. 15, p. 2062-2072
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ISSN: 0039-7911
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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