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http://hdl.handle.net/2445/46043
Title: | Versatile methodology to hydrate alkynes, in the presence of a wide variety of functional groups, with Mercury(II) p-Toluensulfonamidate, under catalytic, mild and neutral conditions |
Author: | Corominas, Albert (Corominas Tarruella) Montaña Pedrero, Ángel-Manuel |
Keywords: | Compostos carbonílics Química orgànica Carbonyl compounds Organic chemistry |
Issue Date: | 2013 |
Publisher: | Taylor and Francis |
Abstract: | A method to generate carbonylic compounds from alkynes under mild and neutral conditions, with excellent functional group compatibility and high yields, is described. Hydration takes place under catalytic conditions by using from 0.1 to 0.2 equivalents of the easily available and inexpensive mercury(II) p-toluensulfonamidate in a hydroalcoholic solution. After use the catalyst is iner tized and/or recycled ... |
Note: | Versió postprint del document publicat a: http://dx.doi.org/10.1080/00397911.2012.686003 |
It is part of: | Synthetic Communications, 2013, vol. 43, num. 15, p. 2062-2072 |
URI: | http://hdl.handle.net/2445/46043 |
Related resource: | http://dx.doi.org/10.1080/00397911.2012.686003 |
ISSN: | 0039-7911 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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623938.pdf | 379.02 kB | Adobe PDF | View/Open |
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