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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/48632
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dc.contributor.authorGeorges, Yohan-
dc.contributor.authorAriza Piquer, Xavier-
dc.contributor.authorGarcía Gómez, Jordi-
dc.date.accessioned2013-12-20T11:53:15Z-
dc.date.available2013-12-20T11:53:15Z-
dc.date.issued2009-
dc.identifier.issn0022-3263-
dc.identifier.urihttp://hdl.handle.net/2445/48632-
dc.description.abstract(-)-Spicigerolide was enantioselectively synthesized from a protected (S)-lactaldehyde. The synthesis of the polyacetylated framework relied on two Zn-mediated stereoselective additions of alkynes to aldehydes as well as a regiocontrolled [3,3]-sigmatropic rearrangement of an allylic acetate. The pyranone moiety was constructed via ring-closing metathesis.-
dc.format.extent16 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofVersió postprint del document publicat a: http://dx.doi.org/10.1021/jo8025753-
dc.relation.ispartofJournal of Organic Chemistry, 2009, vol. 74, num. 5, p. 2008-2012-
dc.relation.urihttp://dx.doi.org/10.1021/jo8025753-
dc.rights(c) American Chemical Society , 2009-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationPlantes-
dc.subject.classificationBotànica mèdica-
dc.subject.classificationCitotoxicitat per mediació cel·lular-
dc.subject.classificationCàncer-
dc.subject.classificationEstereoquímica-
dc.subject.classificationProductes naturals-
dc.subject.classificationSíntesi orgànica-
dc.subject.otherPlants-
dc.subject.otherMedical botany-
dc.subject.otherCell-mediated cytotoxicity-
dc.subject.otherCancer-
dc.subject.otherStereochemistry-
dc.subject.otherNatural products-
dc.subject.otherOrganic synthesis-
dc.titleStereoselective Synthesis of (-)-Spicigerolide-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec565900-
dc.date.updated2013-12-20T11:53:15Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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