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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/54408
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dc.contributor.authorAiguabella Font, Núria-
dc.contributor.authorArce, Elsa M.-
dc.contributor.authorPozo, Carlos del-
dc.contributor.authorVerdaguer i Espaulella, Xavier-
dc.contributor.authorRiera i Escalé, Antoni-
dc.date.accessioned2014-05-22T11:43:34Z-
dc.date.available2014-05-22T11:43:34Z-
dc.date.issued2014-02-03-
dc.identifier.issn1420-3049-
dc.identifier.urihttp://hdl.handle.net/2445/54408-
dc.description.abstractAbstract: The scope of the Pauson-Khand reaction (PKR) of internal trifluoromethyl alkynes, previously described with norbornadiene, is expanded to norbornene and ethylene. A thorough structural analysis of the resulting PK adducts has been carried out to unveil that α-trifluoromethylcyclopentenones are preferred in all cases, independently of the electronic properties of the alkyne. The regioselectivity observed with norbornadiene and ethylene is higher than in the case of norbornene.-
dc.format.extent12 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherMDPI Publishing-
dc.relation.isformatofReproducció del document publicat a: http://doi.dx.org/10.3390/molecules19021763-
dc.relation.ispartofMolecules, 2014, vol. 19, num. 2, p. 1763-1774-
dc.relation.urihttp://dx.doi.org/10.3390/molecules19021763-
dc.rightscc-by (c) Aiguabella Font, Núria et al., 2014-
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationCiclització (Química)-
dc.subject.classificationQuímica organometàl·lica-
dc.subject.classificationCobalt-
dc.subject.otherRing formation (Chemistry)-
dc.subject.otherOrganometallic chemistry-
dc.subject.otherCobalt-
dc.titlePauson-Khand reaction of internal dissymmetric trifluoromethyl alkynes. influence of the alkene on the regioselectivity-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.identifier.idgrec633458-
dc.date.updated2014-05-22T11:43:34Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
dc.identifier.pmid24496269-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)
Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona))

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