Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/68334
Title: Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands
Author: Orgué Gassol, Sílvia
Flores-Gaspar, Areli
Biosca, Maria
Pàmies, Oscar
Diéguez, Montserrat
Riera i Escalé, Antoni
Verdaguer i Espaulella, Xavier
Keywords: Hidròlisi
Lligands
Catàlisi asimètrica
Compostos de bor
Hydrolysis
Ligands
Enantioselective catalysis
Boron compounds
Issue Date: 2-Oct-2015
Publisher: Royal Society of Chemistry
Abstract: The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.
Note: Reproducció del document publicat a: http://dx.doi.org/10.1039/c5cc07504a
It is part of: Chemical Communications, 2015, vol. 51, p. 17548-17551
Related resource: http://dx.doi.org/10.1039/c5cc07504a
URI: http://hdl.handle.net/2445/68334
ISSN: 1359-7345
Appears in Collections:Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona))
Articles publicats en revistes (Química Inorgànica i Orgànica)

Files in This Item:
File Description SizeFormat 
654578.pdf1.41 MBAdobe PDFView/Open


This item is licensed under a Creative Commons License Creative Commons