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http://hdl.handle.net/2445/98695
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DC Field | Value | Language |
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dc.contributor.author | Gil, Alejandro | - |
dc.contributor.author | Lamariano Merketegi, Janire | - |
dc.contributor.author | Lorente Crivillé, Adriana | - |
dc.contributor.author | Albericio Palomera, Fernando | - |
dc.contributor.author | Álvarez Domingo, Mercedes | - |
dc.date.accessioned | 2016-05-19T15:16:32Z | - |
dc.date.available | 2017-05-17T22:01:27Z | - |
dc.date.issued | 2016-05-17 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/2445/98695 | - |
dc.description.abstract | The terminal bromomethoxydiene (BMD) moiety of the polyhydroxylated chain present in phormidolides and oscillariolides has been synthesized for first time. Several strategies for the stereoselective synthesis of the 4-bromo-3-methoxybut-3-en-2-ones are described. Furthermore, a preliminary study to successfully introduce this fragment within the polyol chain and introduction of the fatty acid allowed corroborate the end structure of the polyol. | - |
dc.format.extent | 3 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: http://dx.doi.org/10.1002/chem.201600770 | - |
dc.relation.ispartof | Chemistry-A European Journal, 2016, vol. 22, num. 21, p. 7033-7035 | - |
dc.relation.uri | http://dx.doi.org/10.1002/chem.201600770 | - |
dc.rights | (c) Wiley-VCH, 2016 | - |
dc.source | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) | - |
dc.subject.classification | Productes naturals | - |
dc.subject.classification | Síntesi asimètrica | - |
dc.subject.classification | Química orgànica | - |
dc.subject.other | Natural products | - |
dc.subject.other | Asymmetric synthesis | - |
dc.subject.other | Organic chemistry | - |
dc.title | Synthesis of (E)-4-bromo-3-methoxybut-3-en-2-one, the key fragment in the polyhydroxylated chain common to oscillariolide and phormidolides A-C | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 658455 | - |
dc.date.updated | 2016-05-19T15:16:37Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 26998826 | - |
Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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658455.pdf | 471.91 kB | Adobe PDF | View/Open |
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