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http://hdl.handle.net/2445/99269
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DC Field | Value | Language |
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dc.contributor.author | Amat Tusón, Mercedes | - |
dc.contributor.author | Ghirardi, Elena | - |
dc.contributor.author | Navío, Laura | - |
dc.contributor.author | Griera Farres, Rosa | - |
dc.contributor.author | Llor Brunés, Núria | - |
dc.contributor.author | Molins i Grau, Elies | - |
dc.contributor.author | Bosch Cartes, Joan | - |
dc.date.accessioned | 2016-06-06T15:46:04Z | - |
dc.date.available | 2016-06-06T15:46:04Z | - |
dc.date.issued | 2013-11-18 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/2445/99269 | - |
dc.description.abstract | Up to four stereocenters with a well-defined configuration are generated in a single synthetic step by the cyclocondensation of (R)-phenylglycinol or (1S,2R)-1-amino-2-indanol with stereoisomeric mixtures (racemates, meso forms, diastereoisomers) of cyclohexanone-based δ-keto-acid and δ-keto-diacid derivatives in enantio- and diastereoconvergent processes that involve dynamic kinetic resolution and/or desymmetrization of enantiotopic groups. A detailed analysis of the stereochemical outcome of this process is presented. This method provides easy access to enantiopure 8- and 6,8-substituted cis-decahydroquinolines, including alkaloids of the myrioxazine family. | - |
dc.format.extent | 6 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: http://dx.doi.org/10.1002/chem.201302894 | - |
dc.relation.ispartof | Chemistry-A European Journal, 2013, vol. 19, num. 47, p. 16044-16049 | - |
dc.relation.uri | http://dx.doi.org/10.1002/chem.201302894 | - |
dc.rights | (c) Wiley-VCH, 2013 | - |
dc.source | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) | - |
dc.subject.classification | Química orgànica | - |
dc.subject.classification | Alcaloides | - |
dc.subject.classification | Síntesi asimètrica | - |
dc.subject.classification | Lactames | - |
dc.subject.classification | Compostos heterocíclics | - |
dc.subject.other | Organic chemistry | - |
dc.subject.other | Alkaloids | - |
dc.subject.other | Asymmetric synthesis | - |
dc.subject.other | Lactams | - |
dc.subject.other | Heterocyclic compounds | - |
dc.title | Enantio- and Diastereoconvergent Cyclocondensation Reactions: Synthesis of Enantiopure cis-Decahydroquinolines. | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 628798 | - |
dc.date.updated | 2016-06-06T15:46:09Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 24115323 | - |
Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) Articles publicats en revistes (Institut de Biomedicina (IBUB)) |
Files in This Item:
File | Description | Size | Format | |
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628798.pdf | 878.44 kB | Adobe PDF | View/Open |
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