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http://hdl.handle.net/2445/106619
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DC Field | Value | Language |
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dc.contributor.author | Rodríguez Ramírez, Aleix | - |
dc.contributor.author | Ariza Piquer, Xavier | - |
dc.contributor.author | Contreras, Miguel A. | - |
dc.contributor.author | García Gómez, Jordi | - |
dc.contributor.author | Lloyd-Williams, Paul | - |
dc.contributor.author | Mercadal, Nerea | - |
dc.contributor.author | Sánchez Zarzalejo, Carolina | - |
dc.date.accessioned | 2017-02-07T14:33:36Z | - |
dc.date.available | 2018-02-03T23:01:19Z | - |
dc.date.issued | 2017-02-03 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/2445/106619 | - |
dc.description.abstract | Treatment of readily available allene 1 with Cy2BH followed by addition of an aldehyde led to quaternary protected 2-amino-2-vinyl-1,3-diols in high yield and excellent stereochemical purity. The choice of benzoyl as N-protecting group is critical since the observed N- to O-Bz transfer during the process prevents later undesired isomerizations in the adducts and keeps all heteroatoms protected. | - |
dc.format.extent | 5 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.joc.6b02765 | - |
dc.relation.ispartof | Journal of Organic Chemistry, 2017, vol. 82, num. 3, p. 1851-1855 | - |
dc.relation.uri | https://doi.org/10.1021/acs.joc.6b02765 | - |
dc.rights | (c) American Chemical Society , 2017 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Síntesi orgànica | - |
dc.subject.classification | Aldehids | - |
dc.subject.classification | Esfingolípids | - |
dc.subject.classification | Inhibidors enzimàtics | - |
dc.subject.other | Organic synthesis | - |
dc.subject.other | Aldehydes | - |
dc.subject.other | Sphingolipids | - |
dc.subject.other | Enzyme inhibitors | - |
dc.title | A Useful allene for the stereoselective synthesis of protected quaternary 2-amino-2-vinyl-1,3-diols | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 667388 | - |
dc.date.updated | 2017-02-07T14:33:36Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 28085287 | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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667388.pdf | 406.02 kB | Adobe PDF | View/Open |
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