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Title: Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines
Author: Flores-Gaspar, Areli
Orgué Gassol, Sílvia
Grabulosa, Arnald
Riera i Escalé, Antoni
Verdaguer i Espaulella, Xavier
Keywords: Compostos organometàl·lics
Lligands (Bioquímica)
Catàlisi asimètrica
Organometallic compounds
Ligands (Biochemistry)
Enantioselective catalysis
Issue Date: 22-Dec-2014
Publisher: Royal Society of Chemistry
Abstract: In non-coordinating solvents, borane was shown to be an efficient directing group for the stereoselective 1,2-addition of organolithium reagents to P-stereogenic N-phosphanylimines. Selectivity was reversed in coordinating solvents. This process can lead to novel ligand scaffolds for asymmetric catalysis.
Note: Versió postprint del document publicat a:
It is part of: Chemical Communications, 2014, vol. 51, p. 1941-1944
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ISSN: 1359-7345
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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