Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/108386| Title: | Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines |
| Author: | Flores-Gaspar, Areli Orgué Gassol, Sílvia Grabulosa, Arnald Riera i Escalé, Antoni Verdaguer i Espaulella, Xavier |
| Keywords: | Compostos organometàl·lics Lligands (Bioquímica) Catàlisi asimètrica Organometallic compounds Ligands (Biochemistry) Enantioselective catalysis |
| Issue Date: | 22-Dec-2014 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | In non-coordinating solvents, borane was shown to be an efficient directing group for the stereoselective 1,2-addition of organolithium reagents to P-stereogenic N-phosphanylimines. Selectivity was reversed in coordinating solvents. This process can lead to novel ligand scaffolds for asymmetric catalysis. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c4cc09106j |
| It is part of: | Chemical Communications, 2014, vol. 51, p. 1941-1944 |
| URI: | http://hdl.handle.net/2445/108386 |
| Related resource: | https://doi.org/10.1039/c4cc09106j |
| ISSN: | 1359-7345 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 646126.pdf | 265.3 kB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.