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http://hdl.handle.net/2445/114291
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DC Field | Value | Language |
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dc.contributor.author | Salomó i Prat, Ernest | - |
dc.contributor.author | Prades, Amparo | - |
dc.contributor.author | Riera i Escalé, Antoni | - |
dc.contributor.author | Verdaguer i Espaulella, Xavier | - |
dc.date.accessioned | 2017-07-25T08:38:28Z | - |
dc.date.available | 2018-06-22T22:01:24Z | - |
dc.date.issued | 2017-06-22 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/2445/114291 | - |
dc.description.abstract | The preparation of shelf-stable crystalline salts of tert-butylmethylphosphinous acid borane 1 is described. X-ray analysis of diisopropylammonium tert-butylmethylphosphinite borane 4 revealed the existence of a cyclic hydrogen-bond network in the solid state which accounts for the increased melting point and stability. Dialkylammonium phosphinite boranes are convenient precursors of the chiral tert-butylmethylphosphine fragment. Compound 4 can be directly employed in SN2@P reactions with different nucleophiles to yield valuable P-stereogenic intermediates and ligands. | - |
dc.format.extent | 5 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.joc.7b01180 | - |
dc.relation.ispartof | Journal of Organic Chemistry, 2017 | - |
dc.relation.uri | https://doi.org/10.1021/acs.joc.7b01180 | - |
dc.rights | (c) American Chemical Society, 2017 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Lligands (Bioquímica) | - |
dc.subject.classification | Compostos fosforosos | - |
dc.subject.classification | Catàlisi asimètrica | - |
dc.subject.other | Ligands (Biochemistry) | - |
dc.subject.other | Phosphorus compounds | - |
dc.subject.other | Enantioselective catalysis | - |
dc.title | Dialkylammonium tert-Butylmethylphosphinites: Stable Intermediates for the Synthesis of P-Stereogenic Ligands | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.date.updated | 2017-07-25T08:38:28Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 28640640 | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona)) |
Files in This Item:
File | Description | Size | Format | |
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673028.pdf | 296.38 kB | Adobe PDF | View/Open |
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