Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/119757| Title: | Radical Cyclization of Trichloroacetamides: Synthesis of Lactams |
| Author: | Coussanes, Guilhem Vila, X. Diaba, Faïza Bonjoch i Sesé, Josep |
| Keywords: | Lactames Hidrurs Lactams Hydrides |
| Issue Date: | Jan-2017 |
| Publisher: | Georg Thieme Verlag Stuttgart · New York |
| Abstract: | Trichloroacetamides can act as radical precursors to synthesize nitrogen-containing heterocycles in a variety of processes, mainly involving atom transfer radical cyclizations (ATRC), mediated by Cu(I) or Ru(II) catalysts, and the hydride reductive method, employing either Bu3SnH or (Me3Si)3SiH, or recently NaBH3CN. Additionally, amine-mediated single-electron transfer cyclizations, as well as radical processes promoted by Ni, Fe, Mn, Ti, and Ag, have been developed. |
| Note: | Reproducció del document publicat a: https://doi.org/10.1055/s-0036-1588383 |
| It is part of: | Synthesis, 2017, vol. 49, num. 07, p. 1481-1499 |
| URI: | http://hdl.handle.net/2445/119757 |
| Related resource: | https://doi.org/10.1055/s-0036-1588383 |
| ISSN: | 0039-7881 |
| Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 667665.pdf | 1.18 MB | Adobe PDF | View/Open |
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