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https://hdl.handle.net/2445/125848| Title: | A new trinuclear N-N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine |
| Author: | Gholizadeh Dogaheh, Samira Khanmohammadi, Hamid Sañudo Zotes, Eva Carolina |
| Keywords: | Propietats magnètiques Lligands (Bioquímica) Magnetic properties Ligands (Biochemistry) |
| Issue Date: | 5-Sep-2017 |
| Publisher: | Elsevier Ltd |
| Abstract: | In this paper we report the synthesis of an asymmetric Schiff base ligand derived from hydrazine and its Cu(II) trinuclear coordination complex, [Cu-3(HYDRAV)(2)CI2] (HYDRAV-Cu). The ligand HYDRAVH(2) and the Cu(II) complex HYDRAV-Cu have been crystallographically characterized. HYDRAVH(2) contains a fluorescent naphthyl group and emission properties of both HYDRAVH(2) and HYDRAV-Cu are reported. The magnetic properties of HYDRAV-Cu have been investigated. Hydrazine is an excellent precursor for asymmetric Schiff base ligands that afford antiferromagnetic coupling as shown here for HYDRAV-Cu. (C) 2017 Elsevier Ltd. All rights reserved. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2017.05.010 |
| It is part of: | Polyhedron, 2017, vol. 133, p. 48-53 |
| URI: | https://hdl.handle.net/2445/125848 |
| Related resource: | https://doi.org/10.1016/j.poly.2017.05.010 |
| ISSN: | 0277-5387 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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