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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/127015
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dc.contributor.authorSalomó i Prat, Ernest-
dc.contributor.authorGallen Ortiz, Albert-
dc.contributor.authorSciortino, Giuseppe-
dc.contributor.authorUjaque, Gregori-
dc.contributor.authorGrabulosa, Arnald-
dc.contributor.authorLledós, Agustí (Lledós i Falcó)-
dc.contributor.authorRiera i Escalé, Antoni-
dc.contributor.authorVerdaguer i Espaulella, Xavier-
dc.date.accessioned2018-12-17T14:54:57Z-
dc.date.available2019-11-26T06:10:15Z-
dc.date.issued2018-11-26-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/2445/127015-
dc.description.abstractA novel cationic [IrH(THF)(P,N)(imine)] [BArF] catalyst contg. a P-stereogenic MaxPHOX ligand is described for the direct asym. hydrogenation of N-Me and N-alkyl imines. This is the first catalytic system to attain high enantioselectivity (up to 94% ee) in this type of transformation. The labile THF ligand allows for effective activation and reactivity, even at low temps. D. functional theory calcns. allowed the rationalization of the stereochem. course of the reaction.-
dc.format.extent4 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/jacs.8b11547-
dc.relation.ispartofJournal of the American Chemical Society, 2018, vol. 140, p. 16967-16970-
dc.relation.urihttps://doi.org/10.1021/jacs.8b11547-
dc.rights(c) American Chemical Society , 2018-
dc.subject.classificationCatàlisi asimètrica-
dc.subject.classificationLligands-
dc.subject.classificationHidrogenació-
dc.subject.otherEnantioselective catalysis-
dc.subject.otherLigands-
dc.subject.otherHydrogenation-
dc.titleDirect Asymmetric Hydrogenation of N-Methyl and N-Alkyl Imines with an Ir(III)H Catalyst-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec683625-
dc.date.updated2018-12-17T14:54:58Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
dc.identifier.pmid30475609-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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