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http://hdl.handle.net/2445/127064
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DC Field | Value | Language |
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dc.contributor.author | Climent Biescas, Claudia | - |
dc.contributor.author | Alam, Parvej | - |
dc.contributor.author | Pasha, Sheik Saleem | - |
dc.contributor.author | Kaur, Gurpreet | - |
dc.contributor.author | Choudhury, Angshuman Roy | - |
dc.contributor.author | Laskar, Inamur Rahaman | - |
dc.contributor.author | Alemany i Cahner, Pere | - |
dc.contributor.author | Casanova i Casas, David | - |
dc.date.accessioned | 2018-12-20T08:13:48Z | - |
dc.date.available | 2018-12-20T08:13:48Z | - |
dc.date.issued | 2017-07-06 | - |
dc.identifier.issn | 2050-7526 | - |
dc.identifier.uri | http://hdl.handle.net/2445/127064 | - |
dc.description.abstract | Four new Ir(III) complexes with the general formula [IrHCl(C^N)(PPh3)2] containing different conjugated Schiff base ligands (C^N) have been synthesized and characterized by 1H, 13C, and 31P NMR, HRMS, and IR spectra and one of them by single crystal X-ray diffraction. Their photophysical properties in solution and in the solid state have been analyzed and three main practical results have been obtained: (i) a dual fluorescent and phosphorescent emissive complex in solution, (ii) successful acid/base sensing in the solid state and (iii) quantitative CO2 detection. Quantum chemical calculations have been employed to assign the character of the lowest excited states. A plausible explanation for the observed aggregation induced enhanced emission (AIEE) is given, based on the restriction of intramolecular motions due to the effect of intermolecular C-Hp and C-HCl type interactions upon aggregation. | - |
dc.format.extent | 15 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.1039/c7tc02250f | - |
dc.relation.ispartof | Journal of Materials Chemistry C, 2017, vol. 5, p. 7784-7798 | - |
dc.relation.uri | https://doi.org/10.1039/c7tc02250f | - |
dc.rights | cc by (c) Climent Biescas, Claudia et al., 2017 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.source | Articles publicats en revistes (Ciència dels Materials i Química Física) | - |
dc.subject.classification | Iridi | - |
dc.subject.classification | Lligands | - |
dc.subject.classification | Agregació (Química) | - |
dc.subject.classification | Solubilitat | - |
dc.subject.other | Iridium | - |
dc.subject.other | Ligands | - |
dc.subject.other | Aggregation (Chemistry) | - |
dc.subject.other | Solubility | - |
dc.title | Dual emission and multi-stimuli-response in iiridium(III) complexes with aggregation-induced enhanced emission: application for quantitative CO<sub>2</sub> detection | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 683637 | - |
dc.date.updated | 2018-12-20T08:13:48Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Ciència dels Materials i Química Física) |
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683637.pdf | 4.34 MB | Adobe PDF | View/Open |
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