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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/127737
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dc.contributor.authorSolé Arjó, Daniel-
dc.contributor.authorMariani, Francesco-
dc.contributor.authorBennasar Fèlix, M. Lluïsa-
dc.contributor.authorFernández Cadenas, Israel-
dc.date.accessioned2019-01-30T13:51:43Z-
dc.date.available2019-01-30T13:51:43Z-
dc.date.issued2016-04-15-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/2445/127737-
dc.description.abstractA palladium‐catalyzed carbene insertion into C(sp3)−H bonds leading to pyrrolidines was developed. The coupling reaction can be catalyzed by both Pd0 and PdII, is regioselective, and shows a broad functional group tolerance. This reaction is the first example of palladium‐catalyzed C(sp3)−C(sp3) bond assembly starting from diazocarbonyl compounds. DFT calculations revealed that this direct C(sp3)−H bond functionalization reaction involves an unprecedented concerted metalation-deprotonation step.-
dc.format.extent4 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherWiley-VCH-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1002/anie.201602020-
dc.relation.ispartofAngewandte Chemie-International Edition, 2016, vol. 55, num. 22, p. 6467-6470-
dc.relation.urihttps://doi.org/10.1002/anie.201602020-
dc.rights(c) Wiley-VCH, 2016-
dc.sourceArticles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)-
dc.subject.classificationPal·ladi (Element químic)-
dc.subject.classificationCatàlisi-
dc.subject.classificationSíntesi orgànica-
dc.subject.classificationComplexitat computacional-
dc.subject.classificationQuímica organometàl·lica-
dc.subject.otherPalladium-
dc.subject.otherCatalysis-
dc.subject.otherOrganic synthesis-
dc.subject.otherComputational complexity-
dc.subject.otherOrganometallic chemistry-
dc.titlePalladium-catalyzed intramolecular carbene insertion into C(sp3)-H bonds-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec659135-
dc.date.updated2019-01-30T13:51:43Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
dc.identifier.pmid27079473-
Appears in Collections:Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

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