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http://hdl.handle.net/2445/127737
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DC Field | Value | Language |
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dc.contributor.author | Solé Arjó, Daniel | - |
dc.contributor.author | Mariani, Francesco | - |
dc.contributor.author | Bennasar Fèlix, M. Lluïsa | - |
dc.contributor.author | Fernández Cadenas, Israel | - |
dc.date.accessioned | 2019-01-30T13:51:43Z | - |
dc.date.available | 2019-01-30T13:51:43Z | - |
dc.date.issued | 2016-04-15 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/2445/127737 | - |
dc.description.abstract | A palladium‐catalyzed carbene insertion into C(sp3)−H bonds leading to pyrrolidines was developed. The coupling reaction can be catalyzed by both Pd0 and PdII, is regioselective, and shows a broad functional group tolerance. This reaction is the first example of palladium‐catalyzed C(sp3)−C(sp3) bond assembly starting from diazocarbonyl compounds. DFT calculations revealed that this direct C(sp3)−H bond functionalization reaction involves an unprecedented concerted metalation-deprotonation step. | - |
dc.format.extent | 4 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1002/anie.201602020 | - |
dc.relation.ispartof | Angewandte Chemie-International Edition, 2016, vol. 55, num. 22, p. 6467-6470 | - |
dc.relation.uri | https://doi.org/10.1002/anie.201602020 | - |
dc.rights | (c) Wiley-VCH, 2016 | - |
dc.source | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) | - |
dc.subject.classification | Pal·ladi (Element químic) | - |
dc.subject.classification | Catàlisi | - |
dc.subject.classification | Síntesi orgànica | - |
dc.subject.classification | Complexitat computacional | - |
dc.subject.classification | Química organometàl·lica | - |
dc.subject.other | Palladium | - |
dc.subject.other | Catalysis | - |
dc.subject.other | Organic synthesis | - |
dc.subject.other | Computational complexity | - |
dc.subject.other | Organometallic chemistry | - |
dc.title | Palladium-catalyzed intramolecular carbene insertion into C(sp3)-H bonds | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 659135 | - |
dc.date.updated | 2019-01-30T13:51:43Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 27079473 | - |
Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) |
Files in This Item:
File | Description | Size | Format | |
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659135.pdf | 605.7 kB | Adobe PDF | View/Open |
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