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http://hdl.handle.net/2445/127810
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DC Field | Value | Language |
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dc.contributor.author | Solé Arjó, Daniel | - |
dc.contributor.author | Pérez Janer, Ferran | - |
dc.contributor.author | García-Rodeja Navarro, Yago | - |
dc.contributor.author | Fernández Cadenas, Israel | - |
dc.date.accessioned | 2019-02-01T12:45:30Z | - |
dc.date.available | 2019-02-01T12:45:30Z | - |
dc.date.issued | 2017-01-03 | - |
dc.identifier.issn | 1434-193X | - |
dc.identifier.uri | http://hdl.handle.net/2445/127810 | - |
dc.description.abstract | Sulfonates, sulfonamides, and phosphonates have proven useful nucleophiles for palladium‐catalyzed intramolecular α‐arylation reactions leading to tetrahydroisoquinolines. Although the sulfonate α‐arylation reaction can be successfully combined in a domino process with a broad range of Michael acceptors, only vinyl sulfones can be used in Michael additions when starting from sulfonamides. No domino process was developed with the phosphonate derivative. DFT calculations were carried out to gain more insights into the experimental differences observed in the reactions involving these substrates. | - |
dc.format.extent | 7 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1002/ejoc.201601300 | - |
dc.relation.ispartof | European Journal of Organic Chemistry, 2017, vol. 2017, num. 4, p. 799-805 | - |
dc.relation.uri | https://doi.org/10.1002/ejoc.201601300 | - |
dc.rights | (c) Wiley-VCH, 2017 | - |
dc.source | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) | - |
dc.subject.classification | Pal·ladi (Element químic) | - |
dc.subject.classification | Catàlisi | - |
dc.subject.classification | Sulfamides | - |
dc.subject.classification | Teoria del funcional de densitat | - |
dc.subject.classification | Síntesi orgànica | - |
dc.subject.other | Palladium | - |
dc.subject.other | Catalysis | - |
dc.subject.other | Sulfonamides | - |
dc.subject.other | Density functionals | - |
dc.subject.other | Organic synthesis | - |
dc.title | Exploring Partners for the Domino α‐Arylation/Michael Addition Reaction Leading to Tetrahydroisoquinolines | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 667423 | - |
dc.date.updated | 2019-02-01T12:45:31Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) |
Files in This Item:
File | Description | Size | Format | |
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667423.pdf | 1.09 MB | Adobe PDF | View/Open |
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