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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/127958
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dc.contributor.authorKennington, Stuart C. D.-
dc.contributor.authorGómez Palomino, Alejandro-
dc.contributor.authorSalomó i Prat, Ernest-
dc.contributor.authorRomea, Pedro-
dc.contributor.authorUrpí Tubella, Fèlix-
dc.contributor.authorFont Bardia, Ma. Mercedes-
dc.date.accessioned2019-02-06T10:57:36Z-
dc.date.available2019-06-14T05:10:20Z-
dc.date.issued2018-06-14-
dc.identifier.issn1477-0520-
dc.identifier.urihttp://hdl.handle.net/2445/127958-
dc.description.abstractA comprehensive analysis of the influence of the chiral auxiliary on the α-aminoxylation of titanium(IV) enolates with TEMPO indicated that (S) 4-tert-butyl-1-oxazolidine-2-thione is the most appropriate scaffold to provide a single diastereomer in high yields for a variety of substrates, which converts such a radical reaction into a highly chemo- and stereoselective oxidation-
dc.format.extent10 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherRoyal Society of Chemistry-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/c8ob01074a-
dc.relation.ispartofOrganic & Biomolecular Chemistry, 2018, vol. 16, p. 4807-4815-
dc.relation.urihttps://doi.org/10.1039/c8ob01074a-
dc.rights(c) Kennington, Stuart C. D. et al., 2018-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationTitani-
dc.subject.classificationEstereoquímica-
dc.subject.otherTitanium-
dc.subject.otherStereochemistry-
dc.titleGeneral and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliary-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec681138-
dc.date.updated2019-02-06T10:57:36Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
dc.identifier.pmid29915837-
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