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http://hdl.handle.net/2445/128048
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DC Field | Value | Language |
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dc.contributor.author | Griffiths, Kieran | - |
dc.contributor.author | Mayans Ayats, Júlia | - |
dc.contributor.author | Shipman, Michael A. | - |
dc.contributor.author | Tizzard, Graham J. | - |
dc.contributor.author | Coles, Simon J. | - |
dc.contributor.author | Blight, Barry A. | - |
dc.contributor.author | Escuer Fité, Albert | - |
dc.contributor.author | Kostakis, George E. | - |
dc.date.accessioned | 2019-02-07T16:44:45Z | - |
dc.date.available | 2019-02-07T16:44:45Z | - |
dc.date.issued | 2017-04-01 | - |
dc.identifier.issn | 1528-7483 | - |
dc.identifier.uri | http://hdl.handle.net/2445/128048 | - |
dc.description.abstract | The employment of three structurally related Schiff bases H(2)L1, H(2)L2, and H(3)L3 with zinc and lanthanide salts under various reaction conditions, gave four families of compounds formulated as [Zn(2)(II)Ln(2)(III)(L1)(4)(EtOH)(6)][ClO4](2) (1-3), [Zn(5)(II)Ln(OH)(L1)(6)(H2O)] (4-6), [Zn(4)(II)Ln(2)(III)(OH)(2)(L2)(4) (OAc)(2)(NO3)(2)(DMF)3]center dot DMF (7-9), and [Zn(2)(II)Ln(2)(III)(L3)(2)(NO3)(2) (CO3)(2)(CH3OH)(2)] (10-12) with robust and novel topologies. Synthetic aspects are discussed. A comprehensive topological analysis of all reported Zn-II/Ln(III) CCs with a core nuclearity of four and above is presented and identifies that families (4-6) and (7-9) are the first examples of the 2,3,4M6-1 motif in Zn-II/Ln(III) chemistry. Magnetic studies are presented for the Dy-II analogues (1, 7, and 10) are presented, 7 demonstrates field -induced slow relaxation of the magnetization. Fluorescence studies are also discussed. | - |
dc.format.extent | 15 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.cgd.6b01401 | - |
dc.relation.ispartof | Crystal Growth & Design, 2017, vol. 17, num. 4, p. 1524-1538 | - |
dc.relation.uri | https://doi.org/10.1021/acs.cgd.6b01401 | - |
dc.rights | (c) American Chemical Society , 2017 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Zinc | - |
dc.subject.classification | Magnetisme | - |
dc.subject.classification | Topologia | - |
dc.subject.classification | Metalls de terres rares | - |
dc.subject.other | Zinc | - |
dc.subject.other | Magnetism | - |
dc.subject.other | Topology | - |
dc.subject.other | Rare earth metals | - |
dc.title | Four new families of polynuclear Zn-Ln coordination clusters. Synthetic, topological, magnetic, and luminescent aspects | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 681393 | - |
dc.date.updated | 2019-02-07T16:44:45Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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681393.pdf | 1.08 MB | Adobe PDF | View/Open |
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