Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/128156
Title: | Stereoselective oxidation of titanium(IV) enolates with oxygen |
Author: | Gómez Palomino, Alejandro Romea, Pedro Urpí Tubella, Fèlix |
Keywords: | Titani Estereoquímica Quiralitat Titanium Stereochemistry Chirality |
Issue Date: | 1-Jul-2018 |
Publisher: | Georg Thieme Verlag |
Abstract: | A novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A highly stereoselective oxidation of titanium(IV) enolates from chiral N-acyloxazolidinones is performed with oxygen under simple experimental conditions that do not require any reducing steps. The success of this approach depends on the biradical character of titanium(IV) enolates. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1055/s-0037-1609966 |
It is part of: | Synthesis. Journal of Synthetic Organic Chemistry, 2018, vol. 50, num. 14, p. 2721-2726 |
URI: | http://hdl.handle.net/2445/128156 |
Related resource: | https://doi.org/10.1055/s-0037-1609966 |
ISSN: | 0039-7881 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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