Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/128198
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DC Field | Value | Language |
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dc.contributor.author | Coussanes, Guilhem | - |
dc.contributor.author | Jakobi, Harald | - |
dc.contributor.author | Lindell, Stephen | - |
dc.contributor.author | Bonjoch i Sesé, Josep | - |
dc.date.accessioned | 2019-02-13T11:17:03Z | - |
dc.date.available | 2019-05-16T05:10:17Z | - |
dc.date.issued | 2018-05-16 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/2445/128198 | - |
dc.description.abstract | A cyanoborohydride-promoted radical cyclization methodology has been developed to access α-chlorolactams in a simple and efficient way, using NaBH3CN and trichloroacetamides easily available from allylic and homoallylic secondary amines. This methodology allowed the synthesis of a library of αchlorolactams (mono and bicyclic), which were tested for herbicidal activity, trans-3-chloro-4-methyl-1-(3-trifluoromethyl)phenyl-2-pyrrolidinone being the most active. | - |
dc.format.extent | 6 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1002/chem.201800210 | - |
dc.relation.ispartof | Chemistry-A European Journal, 2018, vol. 24, num. 32, p. 8151-8156 | - |
dc.relation.uri | https://doi.org/10.1002/chem.201800210 | - |
dc.rights | (c) Wiley-VCH, 2018 | - |
dc.source | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) | - |
dc.subject.classification | Lactames | - |
dc.subject.classification | Herbicides | - |
dc.subject.classification | Radicals (Química) | - |
dc.subject.classification | Síntesi orgànica | - |
dc.subject.other | Lactams | - |
dc.subject.other | Herbicides | - |
dc.subject.other | Radicals (Chemistry) | - |
dc.subject.other | Organic synthesis | - |
dc.title | Synthesis of a-chlorolactams by cyanoborohydride-mediated radical cyclization of trichloroacetamides | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 683223 | - |
dc.date.updated | 2019-02-13T11:17:03Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 29603478 | - |
Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) |
Files in This Item:
File | Description | Size | Format | |
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683223.pdf | 383.6 kB | Adobe PDF | View/Open |
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