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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/128365
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dc.contributor.authorDiaba, Faïza-
dc.contributor.authorMontiel Achong, Juan Andrés-
dc.contributor.authorSerban, Georgeta-
dc.contributor.authorBonjoch i Sesé, Josep-
dc.date.accessioned2019-02-18T10:49:20Z-
dc.date.available2019-02-18T10:49:20Z-
dc.date.issued2015-01-21-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/2445/128365-
dc.description.abstractAn unexpected C-C bond cleavage was observed in trichloroacetamide-tethered ketones under amine treatment and exploited to develop a new synthesis of normophans from 4-amidocyclohexanones. The reaction involves an unprecedented intramolecular haloform-type reaction of trichloroacetamides promoted by enamines (generated in situ from ketones) as counter-reagents. The methodology was applied to the synthesis of compounds embodying the 6-azabicyclo[3.2.1]octane framework.-
dc.format.extent4 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.5b01832-
dc.relation.ispartofOrganic Letters, 2015, vol. 2015, num. 17, p. 3860-3863-
dc.relation.urihttps://doi.org/10.1021/acs.orglett.5b01832-
dc.rights(c) American Chemical Society , 2015-
dc.sourceArticles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)-
dc.subject.classificationCetones-
dc.subject.classificationAmines-
dc.subject.classificationSíntesi orgànica-
dc.subject.classificationReaccions químiques-
dc.subject.otherKetones-
dc.subject.otherAmines-
dc.subject.otherOrganic synthesis-
dc.subject.otherChemical reactions-
dc.titleSynthesis of Normorphans through an Efficient Intramolecular Carbamoylation of Ketones-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec654621-
dc.date.updated2019-02-18T10:49:20Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
dc.identifier.pmid26197207-
Appears in Collections:Articles publicats en revistes (Institut de Biomedicina (IBUB))
Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

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