Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/128486
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Vásquez Espinal, Alejandro | - |
dc.contributor.author | Poater i Teixidor, Jordi | - |
dc.contributor.author | Solà, Miquel | - |
dc.contributor.author | Tiznado, Willian | - |
dc.contributor.author | Islas, Rafael | - |
dc.date.accessioned | 2019-02-20T09:23:18Z | - |
dc.date.available | 2019-02-20T09:23:18Z | - |
dc.date.issued | 2017-02-07 | - |
dc.identifier.issn | 1144-0546 | - |
dc.identifier.uri | http://hdl.handle.net/2445/128486 | - |
dc.description.abstract | The objective of the current work is to evaluate the effectiveness of the isoelectronic substitution (IS) principle on a series of complexes with the general formula OsCl2(SX3H3)(PH3)(2), where X-3 represents the moieties CCC, CCB, CCN, CBN, CNB or NCB, formed by substitution of the carbon atoms in CCC by either the isoelectronic B- or N+ separately, or by both. The SX3H3 moiety forms, together with Os, an aromatic five-membered ring (5-MR) called osmathiophene. The preservation of stability and aromaticity in the resulting systems is used to indicate the effectiveness of the IS principle. The aromaticity of the proposed molecules is analyzed according to the magnetic (induced magnetic field (B-ind)) and electronic (through the multicenter index (MCI)) criteria. In addition a chemical bonding analysis on selected species is performed by the adaptive natural density partitioning (AdNDP) method. | - |
dc.format.extent | 11 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/c6nj02972h | - |
dc.relation.ispartof | New Journal of Chemistry, 2017, vol. 41, num. 3, p. 1168-1178 | - |
dc.relation.uri | https://doi.org/10.1039/c6nj02972h | - |
dc.rights | (c) Vásquez Espinal, Alejandro et al., 2017 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Reaccions de substitució | - |
dc.subject.classification | Compostos aromàtics | - |
dc.subject.classification | Compostos inorgànics | - |
dc.subject.other | Substitution reactions | - |
dc.subject.other | Aromatic compounds | - |
dc.subject.other | Inorganic compounds | - |
dc.title | Testing the effectiveness of the isoelectronic substitution principle through the transformation of aromatic osmathiophene derivatives into their inorganic analogues | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 676638 | - |
dc.date.updated | 2019-02-20T09:23:18Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Institut de Química Teòrica i Computacional (IQTCUB)) Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
676638.pdf | 1.02 MB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.