Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/139356
Title: | A voltammetric electronic tongue based on commercial screen-printed electrodes for the analysis of aminothiols by differential pulse voltammetry |
Author: | Pérez Ràfols, Clara Gómez, Ana Serrano i Plana, Núria Díaz Cruz, José Manuel Ariño Blasco, Cristina Esteban i Cortada, Miquel |
Keywords: | Voltametria Electroquímica Voltammetry Electrochemistry |
Issue Date: | Mar-2017 |
Publisher: | Wiley-VCH |
Abstract: | A voltammetric electronic tongue has been designed as a proof of concept for the analysis of aminothiols by differential pulse voltammetry and has been tested in ternary mixtures of cysteine (Cys), homocysteine (hCys) and glutathione (GSH). It consists of three screen-printed electrodes of carbon, carbon nanofibers and gold cured at low temperature. A preliminary calibration study carried out separately for each aminothiol confirmed that, working at an optimal pH value of 7.4, every electrode produces differentiated responses for every analyte (cross-response). As for the tongue, it was applied to calibration and validation mixtures of Cys, hCys and GSH and provided voltammograms that, baseline-corrected, normalized and combined in different ways were submitted to partial least squares (PLS) calibration. The calibration models produced good predictions of the concentrations of all three analytes, which suggest that the proposed voltammetric tongue improves the performance of a previous design based on linear sweep voltammetric measurements under acidic conditions. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1002/elan.201700053 |
It is part of: | Electroanalysis, 2017, vol. 29, p. 1559 -1565 |
URI: | http://hdl.handle.net/2445/139356 |
Related resource: | https://doi.org/10.1002/elan.201700053 |
ISSN: | 1040-0397 |
Appears in Collections: | Articles publicats en revistes (Enginyeria Química i Química Analítica) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
670593.pdf | 347.16 kB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.