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http://hdl.handle.net/2445/139424Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Rosado Piquer, Lidia | - |
| dc.contributor.author | Dey, S. | - |
| dc.contributor.author | Teat, Simon J. | - |
| dc.contributor.author | Cirera Fernández, Jordi | - |
| dc.contributor.author | Rajaraman, Gopalan | - |
| dc.contributor.author | Sañudo Zotes, Eva Carolina | - |
| dc.date.accessioned | 2019-09-06T08:23:46Z | - |
| dc.date.available | 2020-08-19T05:10:26Z | - |
| dc.date.issued | 2019-08-19 | - |
| dc.identifier.issn | 1477-9226 | - |
| dc.identifier.uri | http://hdl.handle.net/2445/139424 | - |
| dc.description.abstract | In this paper we describe the synthesis and magnetic properties of a series of 3d-4f complexes of general formula [M4Ln(OH)2(chp)4(SALOH)5(H2O)(MeCN)(Solv)] (Solv = MeOH, MeCN, H2O; chp stands for deprotonated 6-chloro-2-hydroxypyridine (C5H3ClNO), SALOH stands for monodeprotonated 3,5-ditert-butylsalicylic acid (C15H21O3)) obtained by a solvent-free microwave assisted synthesis method. The Ni(II) complexes (Ni4Gd, Solv = MeOH; Ni4Dy, Solv = MeCN) are not SMMs in the absence of an applied dc field. The replacement of Ni(II) by Co(II) (Co4La, Solv = MeOH; Co4Gd, Solv = H2O; Co4Gd-MeCN, Solv = MeCN; Co4Tb, Solv = MeOH; Co4Dy, Solv = H2O) results in improved SMM properties. | - |
| dc.format.extent | 11 p. | - |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | Royal Society of Chemistry | - |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/C9DT02567G | - |
| dc.relation.ispartof | Dalton Transactions, 2019, vol. 48, p. 12440-12450 | - |
| dc.relation.uri | https://doi.org/10.1039/C9DT02567G | - |
| dc.rights | (c) Rosado Piquer, Lidia et al., 2019 | - |
| dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
| dc.subject.classification | Compostos metàl·lics | - |
| dc.subject.classification | Propietats magnètiques | - |
| dc.subject.other | Metallic composites | - |
| dc.subject.other | Magnetic properties | - |
| dc.title | Microwave assisted synthesis of heterometallic 3d-4f M4Ln complexes | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/acceptedVersion | - |
| dc.identifier.idgrec | 691144 | - |
| dc.date.updated | 2019-09-06T08:23:47Z | - |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 691144.pdf | 1.05 MB | Adobe PDF | View/Open |
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