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http://hdl.handle.net/2445/143161
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DC Field | Value | Language |
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dc.contributor.author | Del Horno, Estefanía | - |
dc.contributor.author | Jover Modrego, Jesús | - |
dc.contributor.author | Mena, Miguel | - |
dc.contributor.author | Pérez-Redondo, Adrián | - |
dc.contributor.author | Yélamos, Carlos | - |
dc.date.accessioned | 2019-10-25T08:16:42Z | - |
dc.date.available | 2020-12-31T06:10:17Z | - |
dc.date.issued | 2019 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/2445/143161 | - |
dc.description.abstract | Titanium(III) complexes containing unprecedented (NH2BH2NHBH3) 2‒ and {N(BH3)3} 3‒ ligands have been isolated and their structures elucidated by a combination of experimental and theoretical methods. The treatment of the trimethyl derivative [TiCp*Me3] (Cp* = η5 -C5Me5) with NH3BH3 (3 equiv) at room temperature gives the paramagnetic dinuclear complex [{TiCp*(NH2BH3)}2(µ-NH2BH2NHBH3)], which at 80 ºC leads to the trinuclear hydride derivative [{TiCp*(µ-H)}3{µ3-N(BH3)3}]. The bonding modes of the anionic BN fragments in those complexes as well as the dimethylaminoborane group trapped on the analogous trinuclear [{TiCp*(µ-H)}3(µ3-H)(µ3-NMe2BH2)] have been studied by X | - |
dc.format.extent | 5 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: | - |
dc.relation.ispartof | Chemistry-A European Journal, 2019, vol. 25, p. 7096-7100 | - |
dc.rights | (c) Wiley-VCH, 2019 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Titani | - |
dc.subject.classification | Radiocristal·lografia | - |
dc.subject.classification | Teoria del funcional de densitat | - |
dc.subject.other | Titanium | - |
dc.subject.other | X-ray crystallography | - |
dc.subject.other | Density functionals | - |
dc.title | Ammonia-borane derived BN fragments trapped on bi- and trimetallic titanium(III) systems | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 691272 | - |
dc.date.updated | 2019-10-25T08:16:42Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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691272.pdf | 3.13 MB | Adobe PDF | View/Open |
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