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http://hdl.handle.net/2445/143360
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DC Field | Value | Language |
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dc.contributor.author | Álvarez Yebra, Rubén | - |
dc.contributor.author | Rojo, Pep | - |
dc.contributor.author | Riera i Escalé, Antoni | - |
dc.contributor.author | Verdaguer i Espaulella, Xavier | - |
dc.date.accessioned | 2019-10-28T16:38:27Z | - |
dc.date.available | 2021-04-16T05:10:18Z | - |
dc.date.issued | 2019-04-16 | - |
dc.identifier.issn | 0040-4020 | - |
dc.identifier.uri | http://hdl.handle.net/2445/143360 | - |
dc.description.abstract | The synthesis of optically and diastereomerically pure P-stereogenic phosphine-imidazole ligands is reported. The new ligands contain either a benzoimidazole or a 4-phenylimidazole as a N-donor fragment. The ligands were coordinated to iridium and the structure of the corresponding cationic COD complexes was detd. by x-ray anal. The combination of the chiral phosphorus atom and the imidazole substituents generate a strong chiral environment around the metal center. Preliminary hydrogenation reactions with a model cyclic β-enamide are also reported. | - |
dc.format.extent | 7 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.tet.2019.04.032Get | - |
dc.relation.ispartof | Tetrahedron, 2019, vol. 75, num. 32, p. 4358-4364 | - |
dc.relation.uri | https://doi.org/10.1016/j.tet.2019.04.032Get | - |
dc.rights | cc-by-nc-nd (c) Elsevier B.V., 2019 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Lligands | - |
dc.subject.classification | Iridi | - |
dc.subject.classification | Hidrogenació | - |
dc.subject.other | Ligands | - |
dc.subject.other | Iridium | - |
dc.subject.other | Hydrogenation | - |
dc.title | Iridium complexes with P-stereogenic phosphino imidazole ligands: Synthesis, structure and catalysis | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 692335 | - |
dc.date.updated | 2019-10-28T16:38:28Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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File | Description | Size | Format | |
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692335.pdf | 678.97 kB | Adobe PDF | View/Open |
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