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http://hdl.handle.net/2445/154134
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DC Field | Value | Language |
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dc.contributor.author | Salinas Uber, Jorge | - |
dc.contributor.author | Barrios Moreno, Leoní Alejandra | - |
dc.contributor.author | Estrader i Bofarull, Marta | - |
dc.contributor.author | Roubeau, Olivier | - |
dc.contributor.author | Aromí Bedmar, Guillem | - |
dc.date.accessioned | 2020-03-27T10:28:16Z | - |
dc.date.available | 2021-01-13T06:10:18Z | - |
dc.date.issued | 2020-01-13 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.uri | http://hdl.handle.net/2445/154134 | - |
dc.description.abstract | We present here the design and preparation of several discrete coordination complexes exhibiting two Cu(II) ions separated by a dithienylcyclopentene as a photoswitchable spacer, proposed as models of molecular √SWAP quantum gates. These models use the two Cu(II) ions as realizations of qubits and the spacer as a light switch intended to trigger the gate by reversibly undergoing a ring closing isomerization. For this, a dicarboxylate species with a central diarylethene, H2L1, has been used, together with bipyridine or phenantroline as capping ligands. Also, a new dinucleating ligand containing the photoactive moiety between two tridentate coordinating pockets, H4L2, has been designed and prepared for the same purpose. The four complexes have been characterized by single-crystal X-ray diffraction. Three of them exhibit reversible photoswitching in solution. | - |
dc.format.extent | 7 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1002/ejic.201901141 | - |
dc.relation.ispartof | European Journal of Inorganic Chemistry, 2020, vol. 6, p. 561-567 | - |
dc.relation.uri | https://doi.org/10.1002/ejic.201901141 | - |
dc.rights | (c) Wiley-VCH, 2020 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Fluorescència | - |
dc.subject.classification | Fotoquímica | - |
dc.subject.classification | Coure | - |
dc.subject.other | Fluorescence | - |
dc.subject.other | Photochemistry | - |
dc.subject.other | Copper | - |
dc.title | Dinuclear copper(II) complexes exhibiting reversible photochromism | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 696426 | - |
dc.date.updated | 2020-03-27T10:28:16Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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696426.pdf | 740.61 kB | Adobe PDF | View/Open |
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