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http://hdl.handle.net/2445/154179| Title: | Gas adsorption, magnetism, and single-crystal to single-crystal transformation studies of a three-dimensional Mn(II) porous coordination polymer |
| Author: | Agarwal, Rashmi A. Mukherjee, Soumya Sañudo Zotes, Eva Carolina Ghosh, Sujit K Bharadwaj, Parimal K |
| Keywords: | Lligands Química organometàl·lica Ligands Organometallic chemistry |
| Issue Date: | 21-Oct-2014 |
| Publisher: | American Chemical Society |
| Abstract: | A porous coordination polymer {[Mn2(DBIBA)3]×(NO3)·3DMF·4H2O}n (1) [DBIBAH = 3,5-di(1H-benzo[d]imidazol-1-yl)benzoic acid] has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction. This compound shows significant selective CO2 uptake at low temperature. 1 exhibits antiferromagnetic properties below 17 K, confirmed by magnetic susceptibility measurements. Four new coordination polymers: {[Mn2(DBIBA)3]·ClO4·3DMF·3H2O}n (2), {[Mn2(DBIBA)3]×Cl×DMF×H2O}n (3), {[Mn2(DBIBA)3]×NO3×CH3OH×7H2O}n (4) and {[Mn2(DBIBA)3]×NO3×2CH3COCH3×H2O}n (5), have been synthesized from 1 via anion/solvent exchange protocols at room temperature. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1021/cg500833s |
| It is part of: | Crystal Growth & Design, 2014, vol. 14, num. 11, p. 5585-5592 |
| URI: | http://hdl.handle.net/2445/154179 |
| Related resource: | https://doi.org/10.1021/cg500833s |
| ISSN: | 1528-7483 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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| 655077.pdf | 6.17 MB | Adobe PDF | View/Open |
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