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Title: Gas adsorption, magnetism, and single-crystal to single-crystal transformation studies of a three-dimensional Mn(II) porous coordination polymer
Author: Agarwal, Rashmi A.
Mukherjee, Soumya
Sañudo Zotes, Eva Carolina
Ghosh, Sujit K
Bharadwaj, Parimal K
Keywords: Lligands
Química organometàl·lica
Organometallic chemistry
Issue Date: 21-Oct-2014
Publisher: American Chemical Society
Abstract: A porous coordination polymer {[Mn2(DBIBA)3]×(NO3)·3DMF·4H2O}n (1) [DBIBAH = 3,5-di(1H-benzo[d]imidazol-1-yl)benzoic acid] has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction. This compound shows significant selective CO2 uptake at low temperature. 1 exhibits antiferromagnetic properties below 17 K, confirmed by magnetic susceptibility measurements. Four new coordination polymers: {[Mn2(DBIBA)3]·ClO4·3DMF·3H2O}n (2), {[Mn2(DBIBA)3]×Cl×DMF×H2O}n (3), {[Mn2(DBIBA)3]×NO3×CH3OH×7H2O}n (4) and {[Mn2(DBIBA)3]×NO3×2CH3COCH3×H2O}n (5), have been synthesized from 1 via anion/solvent exchange protocols at room temperature.
Note: Versió postprint del document publicat a:
It is part of: Crystal Growth & Design, 2014, vol. 14, num. 11, p. 5585-5592
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ISSN: 1528-7483
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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