Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/154182
Title: | Characterization of a robust Co-II fluorescent complex deposited intact on HOPG |
Author: | Heras Ojea, M. J. Maneru, Daniel Reta Rosado Piquer, Lidia Rubio Zuazo, Juan Castro, German R. Tewary, Subrata Rajaraman, Gopalan Aromí Bedmar, Guillem Jiménez Romero, Erika Sañudo Zotes, Eva Carolina |
Keywords: | Cobalt Lligands Química de superfícies Pel·lícules fines Cobalt Ligands Surface chemistry Thin films |
Issue Date: | 11-Aug-2014 |
Publisher: | Wiley-VCH |
Abstract: | The new diimine fluorescent ligand ACRI-1 based on a central acridine yellow core is reported along with its coordination complex [Co-2(ACRI-1)(2)] (1), a fluorescent weak ferromagnet. Due to the strong fluorescence of the acridine yellow fluorophore, it is not completely quenched when the ligand is coordinated to Co-II. The magnetic properties of bulk complex 1 and its stability in solution have been studied. Complex 1 has been deposited on highly ordered pyrolitic graphite (HOGP) from solution. The thin films prepared have been characterized by AFM, time-of-flight secondary ion mass spectrometry (TOF-SIMS), grazing incidence X-ray diffraction (GIXRD), X-ray absorption spectroscopy (XAS), X-ray magnetic circular dichroism (XMCD) and theoretical calculations. The data show that the complex is robust and remains intact on the surface of graphite. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1002/chem.201402814 |
It is part of: | Chemistry-A European Journal, 2014, vol. 20, num. 33, p. 10439-10445 |
URI: | http://hdl.handle.net/2445/154182 |
Related resource: | https://doi.org/10.1002/chem.201402814 |
ISSN: | 0947-6539 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
643606.pdf | 3.19 MB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.