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Title: Designed asymmetric coordination helicates with bis-beta-diketonate ligands
Author: Diego, Rosa
Darawsheh, Mohanad D.
Barrios Moreno, Leoní Alejandra
Sadurní, Anna
Garcia-Anton, Jordi
Lloyd-Williams, Paul
Teat, Simon J.
Roubeau, Olivier
Aguilà Avilés, David
Aromí Bedmar, Guillem
Keywords: Lligands
Difracció de raigs X
X-rays diffraction
Issue Date: 23-Nov-2019
Publisher: Royal Society of Chemistry
Abstract: A new bis-(β-diketone) ligand featuring built-up structural asymmetry yields non-symmetric Fe(iii) and Ga(iii) dinuclear, triple-stranded helicates by design. Their structural properties have been studied, both in solid state and in solution, and compared with their corresponding symmetric analogues. The robustness observed shows the potential of this synthetic strategy to develop non-symmetric helicoidal motifs with specific functional groups. © 2019 The Royal Society of Chemistry.
Note: Versió postprint del document publicat a:
It is part of: Dalton Transactions, 2019, vol. 48, num. 45, p. 16844-16847
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ISSN: 1477-9226
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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