Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/154388
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ledezma Gairaud, Marisol | - |
dc.contributor.author | Pineda, L.W. | - |
dc.contributor.author | Aromí Bedmar, Guillem | - |
dc.contributor.author | Sañudo Zotes, Eva Carolina | - |
dc.date.accessioned | 2020-03-30T10:15:14Z | - |
dc.date.available | 2020-03-30T10:15:14Z | - |
dc.date.issued | 2015-06-09 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.uri | http://hdl.handle.net/2445/154388 | - |
dc.description.abstract | Microwave assisted synthesis and bench-top reactions are compared for Mn and Mn/Ni reaction systems with substituted salicylic acid (2-hydroxy-6-isopropyl-3-methylbenzoic-acid (SALOH2). When Mn salts are used, the microwave assisted synthesis and the bench-top reaction afford the same product: the new octanuclear Mn(II)/Mn(III) complex [Mn8O2(OMe)2Cl2(SALO)6(MeOH)4(H2O)2] (1). However, in a mixed metal Mn/Ni reaction the bench-top reaction results in the new heterometallic distorted cubane complexes [Pr2NH2][Mn2Ni2(OH)2(L1)2(SALO)2(SALOH)3] (where L1H = 3-dimethylamino-1-propanol), (2) and [Pr2NH2][Mn2Ni2(OH)(OMe)2(L1)(MeCN)(SALO)2(SALOH)3] (3). The crystal structure and magnetic properties of the prepared complexes are presented. | - |
dc.format.extent | 6 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.ica.2015.05.030 | - |
dc.relation.ispartof | Inorganica Chimica Acta, 2015, vol. 434, p. 215-220 | - |
dc.relation.uri | https://doi.org/10.1016/j.ica.2015.05.030 | - |
dc.rights | cc-by (c) Mognon, Lorenzo et al. | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Lligands | - |
dc.subject.classification | Propietats magnètiques | - |
dc.subject.other | Ligands | - |
dc.subject.other | Magnetic properties | - |
dc.title | Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 653128 | - |
dc.date.updated | 2020-03-30T10:15:14Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
653128.pdf | 904 kB | Adobe PDF | View/Open |
This item is licensed under a
Creative Commons License