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http://hdl.handle.net/2445/154553
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DC Field | Value | Language |
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dc.contributor.author | Oyarzabal, I. | - |
dc.contributor.author | Ruiz Dueñas, J. | - |
dc.contributor.author | Ruiz Sabín, Eliseo | - |
dc.contributor.author | Aravena Ponce, Daniel Alejandro | - |
dc.contributor.author | Seco, J. M. | - |
dc.contributor.author | Colacio, Enrique | - |
dc.date.accessioned | 2020-03-31T15:22:20Z | - |
dc.date.available | 2020-03-31T15:22:20Z | - |
dc.date.issued | 2015-06-17 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/2445/154553 | - |
dc.description.abstract | The trinuclear complex [ZnCl(l-L)Dy(l-L)ClZn]PF6 exhibits a single- molecule magnetic behaviour under zero field with a relatively large effective energy barrier of 186 cm1. Ab initio calculations reveal that the relaxation of the magnetization is symmetry-driven (the DyIII ion possesses a C2 symmetry) and occurs via the second excited state. | - |
dc.format.extent | 4 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/c5cc04495b | - |
dc.relation.ispartof | Chemical Communications, 2015, vol. 51, num. 62, p. 12353-12356 | - |
dc.relation.uri | https://doi.org/10.1039/c5cc04495b | - |
dc.rights | (c) Oyarzabal, I. et al., 2015 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Magnetisme | - |
dc.subject.classification | Ions metàl·lics | - |
dc.subject.other | Magnetism | - |
dc.subject.other | Metal ions | - |
dc.title | Increasing the effective energy barrier promoted by the change of a counteranion in a Zn-Dy-Zn SMM: slow relaxation via the second excited state | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 656357 | - |
dc.date.updated | 2020-03-31T15:22:21Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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656357.pdf | 2.18 MB | Adobe PDF | View/Open |
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