Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/154598
Title: A trinuclear CuII complex with functionalized s-heptazine N-ligands: molecular chemistry from a g-C3N4 fragment
Author: Maxwell Villacorta, Lindley Andrés
Gómez Coca, Silvia
Weyhermüller, Thomas
Panyella, David
Ruiz Sabín, Eliseo
Keywords: Fotocatàlisi
Química supramolecular
Photocatalysis
Supramolecular chemistry
Issue Date: 29-Jul-2015
Publisher: Royal Society of Chemistry
Abstract: A new kind of N-ligands based on heptazine derivatives is presented. A trinuclear CuII complex, [(L)2CuII3Cl3](ClO4)3·3CH2Cl2 (L=2,5,8-tris-(di-2-pyrildylamine) heptazine), utilizing a pyridine derivative of heptazine has been synthesized and characterized avoiding the inherent solubility problems of heptazine compounds. Thus, this work opens the application of such ligands either in supramolecular chemistry as a larger ligand of the widely used s-triazine derivatives or to provide molecular systems for photocatalysis as heptazine is the fundamental unit of the very promising g-C3N4 2D compound.
Note: Versió postprint del document publicat a: https://doi.org/10.1039/c5dt02485d
It is part of: Dalton Transactions, 2015, vol. 44, num. 36, p. 15761-15763
URI: http://hdl.handle.net/2445/154598
Related resource: https://doi.org/10.1039/c5dt02485d
ISSN: 1477-9226
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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