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http://hdl.handle.net/2445/156718
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DC Field | Value | Language |
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dc.contributor.author | Gavara, Raquel | - |
dc.contributor.author | Pinto Martínez, Andrea | - |
dc.contributor.author | Donamaría, Rocío | - |
dc.contributor.author | Olmos, M. Elena | - |
dc.contributor.author | López de Luzuriaga, José M. | - |
dc.contributor.author | Rodríguez Raurell, Laura | - |
dc.date.accessioned | 2020-04-22T08:22:49Z | - |
dc.date.available | 2020-04-22T08:22:49Z | - |
dc.date.issued | 2017-10-02 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/2445/156718 | - |
dc.description.abstract | Reaction of [Au(C6F5)(tht)] (tht = tetrahydrothiophene) with 1,3,5-triaza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]-nonane (DAPTA) leads to the formation of [Au(C6F5)(phosph)] (phosph = PTA, 1; phosph = DAPTA, 2). The compounds are slightly soluble in water and aggregate at higher concentrations giving rise to the formation of needle- and rod-like structures (1) and well-organized spherical aggregates (2). Compounds 1 and 2 were reacted with AgPF6 giving rise to the formation in all cases of luminescent water soluble 1:1 Au·Ag heterometallic complexes, as evidenced by X-ray crystal structure determination. The use of different silver salts that differ on the counterion induces changes on the resulting luminescence and aggregation morphology. | - |
dc.format.extent | 10 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.7b01901 | - |
dc.relation.ispartof | Inorganic Chemistry, 2017, vol. 56, num. 19, p. 11946-11955 | - |
dc.relation.uri | https://doi.org/10.1021/acs.inorgchem.7b01901 | - |
dc.rights | (c) American Chemical Society , 2017 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Anions | - |
dc.subject.classification | Or | - |
dc.subject.classification | Compostos d'or | - |
dc.subject.classification | Argent | - |
dc.subject.classification | Agregació (Química) | - |
dc.subject.other | Anions | - |
dc.subject.other | Gold | - |
dc.subject.other | Gold compounds | - |
dc.subject.other | Silver | - |
dc.subject.other | Aggregation (Chemistry) | - |
dc.title | Polarized supramolecular aggregates based on luminescent perhalogenated gold derivatives | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 673478 | - |
dc.date.updated | 2020-04-22T08:22:51Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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673478.pdf | 1.19 MB | Adobe PDF | View/Open |
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