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https://hdl.handle.net/2445/159621| Title: | First evidence of light-induced spin transition in molybdenum (IV) |
| Author: | Bridonneau, Nathalie Long, J. Cantin, Jean-Louis von Bardeleben, J. Pillet, S. Bendeif, E.E. Aravena Ponce, Daniel Alejandro Ruiz Sabín, Eliseo Marvaud, Valerie |
| Keywords: | Compostos de coordinació Molibdè Zinc Difracció de raigs X Coordination compounds Molybdenum Zinc X-rays diffraction |
| Issue Date: | 25-May-2015 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | Photo-induced spin transition in a molybdenum-zinc complex has been evidenced and fully characterized by Squid magnetometry and several spectroscopies performed under irradiation (IR, EPR, etc.). The phenomenon has been confirmed by X-ray diffraction and DFT calculations yielding a Light-Induced Excited Spin State Trapping Effect (LIESST) on a 4d transition metal ion. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c5cc01714a |
| It is part of: | Chemical Communications, 2015, vol. 51, num. 39, p. 8229-8232 |
| URI: | https://hdl.handle.net/2445/159621 |
| Related resource: | https://doi.org/10.1039/c5cc01714a |
| ISSN: | 1359-7345 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 653204.pdf | 1.71 MB | Adobe PDF | View/Open |
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