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http://hdl.handle.net/2445/159735| Title: | Iron hydride radical reductive alkylation of unactivated alkenes |
| Author: | Saladrigas, Mar Bonjoch i Sesé, Josep Bradshaw, Ben |
| Keywords: | Alquens Hidrogen Alkenes Hydrogen |
| Issue Date: | 30-Dec-2019 |
| Publisher: | American Chemical Society |
| Abstract: | Iron-catalyzed hydrogen atom transfer-mediated intermolecular C−C coupling reactions between alkenes and tosylhydrazones, followed by in situ cleavage of the tosylhydrazine intermediates using Et3N, are described. The process involves a new strategic bond disconnection resulting in the reductive alkylation of nonactivated alkenes. The reaction is operationally simple, proceeds under mild conditions, and has a wide substrate scope. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.9b04459 |
| It is part of: | Organic Letters, 2019, vol. 22, num. 2, p. 684-688 |
| URI: | http://hdl.handle.net/2445/159735 |
| Related resource: | https://doi.org/10.1021/acs.orglett.9b04459 |
| ISSN: | 1523-7060 |
| Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) Articles publicats en revistes (Institut de Biomedicina (IBUB)) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 698797.pdf | 663.54 kB | Adobe PDF | View/Open |
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