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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/160238
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dc.contributor.authorBlanco, Celia-
dc.contributor.authorRibó i Trujillo, Josep M.-
dc.contributor.authorCrusats i Aliguer, Joaquim-
dc.contributor.authorEl Hachemi, Zoubir-
dc.contributor.authorMoyano i Baldoire, Albert-
dc.date.accessioned2020-05-14T10:23:51Z-
dc.date.available2020-05-14T10:23:51Z-
dc.date.issued2013-03-07-
dc.identifier.issn1463-9076-
dc.identifier.urihttp://hdl.handle.net/2445/160238-
dc.description.abstractWe analyze limited enantioselective (LES) autocatalysis in a temperature gradient and with internal flow/recycling of hot and cold material. Microreversibility forbids broken mirror symmetry for LES in the presence of a temperature gradient alone. This symmetry can be broken however when the auto-catalysis and limited enantioselective catalysis are each localized within the regions of low and high temperature, respectively. This scheme has been recently proposed as a plausible model for spontaneous emergence of chirality in abyssal hydrothermal vents. Regions in chemical parameter space are mapped out in which the racemic state is unstable and bifurcates to chiral solutions.-
dc.format.extent11 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherRoyal Society of Chemistry-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/c2cp43488a-
dc.relation.ispartofPhysical Chemistry Chemical Physics, 2013, vol. 15, num. 5, p. 1546-1556-
dc.relation.urihttps://doi.org/10.1039/c2cp43488a-
dc.rights(c) Blanco, Celia et al., 2013-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationQuiralitat-
dc.subject.classificationDicroisme circular-
dc.subject.classificationCatàlisi-
dc.subject.classificationEnantiòmers-
dc.subject.otherChirality-
dc.subject.otherCircular dichroism-
dc.subject.otherCatalysis-
dc.subject.otherEnantiomers-
dc.titleMirror symmetry breaking with limited enantioselective autocatalysis and temperature gradients: a stability survey-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec622795-
dc.date.updated2020-05-14T10:23:52Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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