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http://hdl.handle.net/2445/160462
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DC Field | Value | Language |
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dc.contributor.author | Escuer Fité, Albert | - |
dc.contributor.author | Mayans Ayats, Júlia | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.date.accessioned | 2020-05-15T09:02:07Z | - |
dc.date.available | 2020-05-15T09:02:07Z | - |
dc.date.issued | 2016 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/2445/160462 | - |
dc.description.abstract | The reaction of 2-pyridinemethanol with copper 4-fluorobenzoate has yielded a family of type II cubanes with formula [Cu4(pymO)4(4-F-PhCOO)3(NO3)] (1), [Cu4(pymO)4(4-F-PhCOO)4] (2) and [Cu4(pymO)4(4-F-PhCOO)4(H2O)] (3). These systems exhibit an unexpected S = 1 ground state and their magnetic properties have been unambiguously characterized and rationalized as a function of the asymmetry of the {Cu4O4} cage and Cu-O-Cu bond angles. Analysis of the coupling constants was performed applying new interaction schemes. Magneto-structural correlations have been performed from the analysis of previously reported type II copper cubanes. | - |
dc.format.extent | 32 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/C5DT03643G | - |
dc.relation.ispartof | Dalton Transactions, 2016, vol. 45, num. 4, p. 1604-1613 | - |
dc.relation.uri | https://doi.org/10.1039/C5DT03643G | - |
dc.rights | (c) Escuer Fité, Albert et al., 2016 | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Coure | - |
dc.subject.classification | Magnetisme | - |
dc.subject.other | Copper | - |
dc.subject.other | Magnetism | - |
dc.title | Cooper (II) Cubanes with (Cu4O4) core and well defined S=1 ground state | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 661625 | - |
dc.date.updated | 2020-05-15T09:02:07Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
File | Description | Size | Format | |
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661625.pdf | 1.94 MB | Adobe PDF | View/Open |
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